Tuneable radical cyclisations: a tin-free approach towards tricyclic and spirocyclic heterocycles via a common precursor
Tuneable radical cyclisations: a tin-free approach towards tricyclic and spirocyclic heterocycles via a common precursor
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DOI：
10.1039/c4ra02420f
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发表时间：
2014-04
期刊：
影响因子：
3.9
通讯作者：
B. Patel;G. Saviolaki;C. Ayats;M. A. E. Garcia;T. Kapadia;S. Hilton
中科院分区：
文献类型：
--
作者：
B. Patel;G. Saviolaki;C. Ayats;M. A. E. Garcia;T. Kapadia;S. Hilton
描述了一种新的三环和螺环杂环的共同前体方法。环化基于硫代自由基/异氰化物方法，并避免使用锡。
A novel common precursor approach towards both tricyclic and spirocyclic heterocycles is described. Cyclisations are based on thiyl radical/isocyanide methodology and avoid the use of tin.