Oxidative Functionalization of Methane on Heterogeneous Catalysts
Oxidative Functionalization of Methane on Heterogeneous Catalysts
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DOI：
10.1002/9781119379256.ch8
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发表时间：
2018-12
期刊：
影响因子：
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通讯作者：
M. Sanchez-Sanchez-M.-Sanchez-Sanchez-1398732646;J. Lercher
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文献类型：
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作者：
M. Sanchez-Sanchez-M.-Sanchez-Sanchez-1398732646;J. Lercher
在过去的几十年中，人们对甲烷活化的催化机制有了很多了解。甲烷氧化偶联和氧卤化催化剂的最新进展使这些路线有望实现工业化。对甲烷酶氧化为甲醇的日益深入的了解推动了仿生催化剂的发展。目前，甲烷直接氧化仅实现了非常低的甲醇收率，但该路线巨大的经济潜力引发了该领域的深入研究。主要挑战是从氧气中产生高活性氧物质以及产品的保护。
In the last decades, much knowledge has been gained on catalytic mechanisms for methane activation. Recent advances in catalysts for oxidative coupling and oxyhalogenation of methane make these routes promising for industrial implementation. The increasing understanding of enzymatic oxidation of methane to methanol has motivated the development of biomimetic catalysts. Currently, direct oxidation of methane has only achieved very low methanol yields, but the enormous economic potential of this route has sparked intensive research on the field. The main challenges are generation of highly active oxygen species from O2and protection of the product.