GLYCOSYLIDENE CARBENES .9. FULLERENE SUGARS - PREPARATION OF ENANTIOMERICALLY PURE, SPIRO-LINKED C-GLYCOSIDES OF C-60
GLYCOSYLIDENE CARBENES .9. FULLERENE SUGARS - PREPARATION OF ENANTIOMERICALLY PURE, SPIRO-LINKED C-GLYCOSIDES OF C-60
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DOI：
10.1002/anie.199213881
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发表时间：
1992-10-01
期刊：
影响因子：
--
通讯作者：
THILGEN, C
中科院分区：
文献类型：
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作者：
VASELLA, A;UHLMANN, P;THILGEN, C
“甜巴基球”的产量很高。 C-糖基化、均一、对映体纯的 C60 单加成产物 1（R = 苄基、新戊酰基）的区别不仅在于其手性光学性质，还在于糖基残基的构象，而糖基残基的构象取决于其取代基。
"Sweetened buckyballs" are prepared in good yields. The C-glycosylated, uniform, enantiomerically pure C60 mono-addition products 1 (R = benzyl, pivaloyl) are differentiated not only by their chiroptical properties, but also by the conformation of the glycosyl residue, which is dependent on its substituents.