An active catalytic system for Suzuki Miyaura cross-coupling reactions using low levels of palladium loading
An active catalytic system for Suzuki Miyaura cross-coupling reactions using low levels of palladium loading
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使用低水平钯负载的 Suzuki Miyaura 交叉偶联反应的活性催化系统
DOI：
10.1039/c7o1300178a
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发表时间：
2017
影响因子：
3.2
通讯作者：
Yu Guang Ao
中科院分区：
文献类型：
--
作者：
Yan Meng Qi;Yuan Jia;Lan Fang;Zeng Si Hao;Gao Meng Yue;Liu Sheng Hua;Chen Jian;Yu Guang Ao
开发了一种易于获得的Pd（OAc）2/（2-（蒽-9-基）-1H-茚-3-基）二环己基膦/甲苯/iPrOH/水催化体系，该体系在各种芳基和杂芳基氯化物的Suzuki-Miyaura交叉偶联反应中显示出高的催化活性，Pd负载量低至0.01mol%。
An easily available Pd(OAc)2/(2-(anthracen-9-yl)-1H-inden-3-yl) dicyclohexylphosphine/toluene/iPrOH/water catalytic system was developed, which shows high catalytic activity in the Suzuki–Miyaura cross-coupling reactions of a diverse array of aryl and heteroaryl chlorides with Pd loadings down to 0.01 mol%.