Effect of Solute on Ice-Solution Interfacial Free Energy; Calculation from Measured Homogeneous Nucleation Temperatures

Effect of Solute on Ice-Solution Interfacial Free Energy; Calculation from Measured Homogeneous Nucleation Temperatures
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溶质对冰-溶液界面自由能的影响;

DOI:
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发表时间:
1972
期刊:
影响因子:
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通讯作者:
A. Mackenzie
A. Mackenzie
中科院分区:
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文献类型:
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作者:
D. Rasmussen;A. Mackenzie

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在低温科学家感兴趣的水聚合物界面的形式中,人们特别区分了将冰与固体聚合物分离以及将冰与聚合物水溶液分离的共同表面。冰-固体聚合物界面一直是相当受关注的主题;例如,在1966年的札幌冰雪物理学会议上讨论过,并且是由H. H. G. Jellinek于1967 /2/。相比之下,对冰-水溶液界面的研究主要限于对稀盐溶液中生长速率测量的解释,其中溶液的物理特性主导表面效应的贡献。
Among the forms of the water polymer interface of interest to low temperature scientists one distinguishes in particular the common surfaces separating ice from solid polymer and ice from aqueous polymer solution. The ice — solid polymer interface has been the subject of considerable attention; it was, for example, discussed at the Sapporo Conference on the Physics of Snow and Ice in 1966 /1/ and was the subject of a symposium chaired by Dr. H. H. G. Jellinek in 1967 /2/. Studies on the ice — aqueous solution interface have, in contrast, been limited largely to the interpretation of growth rate measurements in dilute salt solutions /3/, where the physical characteristics of the solution dominate the contribution from the surface effects.