Heteroatom-annulated perylenes: Practical synthesis, photophysical properties, and solid-state packing arrangement
Heteroatom-annulated perylenes: Practical synthesis, photophysical properties, and solid-state packing arrangement
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DOI：
10.1021/jo8012622
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发表时间：
2008-09-19
影响因子：
3.6
通讯作者：
Wang, Zhaohui
中科院分区：
文献类型：
--
作者：
Jiang, Wei;Qian, Hualei;Wang, Zhaohui
提出了一种以高产率制备一系列杂环稠合二萘嵌苯的实用方法。紫外-可见吸收光谱表明吸收最大值相对于相应的母体二萘嵌苯发生了蓝移。单晶X-射线衍射分析表明，），都采用平面构象，但固态包装安排显着改变了各种杂环的成环。
A practical strategy for the preparation of a series of heterocyclic annulated perylenes in good yields is presented. UV-vis absorption spectra indicate hypsochromic shift of the absorption maxima relative to the corresponding parent perylene. Single-crystal X-ray diffraction analysis reveals that the), all adopt planar conformation, but the solid-state packing arrangements are significantly altered by annulation of various heterocycles.