Molecular characterization of glass fiber surface coatings for thermosetting polymer matrix/glass fiber composites
Molecular characterization of glass fiber surface coatings for thermosetting polymer matrix/glass fiber composites
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DOI：
10.1016/s1359-835x(00)00112-3
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发表时间：
2001-01-01
影响因子：
8.7
通讯作者：
McCullough, RL
中科院分区：
文献类型：
--
作者：
Gorowara, RL;Kosik, WE;McCullough, RL
制备具有基于当前专利公开的配方的模型多组分玻璃纤维施胶剂，以模拟商业玻璃纤维制造中使用的全涂层包。该浆料由硅烷偶联剂、成膜剂和水乳化表面活性剂组成，应用于直接由熔融玻璃制备的玻璃纤维。在丙酮提取之前和之后分析纤维。提取液的分析，与纤维分析，用于确定物理和化学吸附层的数量和质量。结果发现，所有三个物种保留在萃取后的纤维上，偶联剂和表面活性剂的浓度在涂料中是高于应用的上浆。这些物种的聚合物复合材料/玻璃纤维界面的影响进行了讨论。(C)2001爱思唯尔科技有限公司版权所有。
Model multi-component glass fiber sizings, with formulations based upon current patent disclosures, were prepared to model the full coating packages used in commercial glass fiber manufacture. The sizings consisted of silane coupling agent, film former, and emulsifying surfactant in water and were applied to glass fibers prepared directly from molten glass. Fibers were analyzed before and after acetone extraction. The analyses of the extract solutions, with the fiber analysis, were used to determine the quantity and quality of the physically and chemically adsorbed layers. It was found that all three species remain on the fiber after extraction and that both coupling agent and surfactant concentrations in the coatings are higher than in the applied sizing. The impact of these species on the polymer composite/glass fiber interphase is discussed. (C) 2001 Elsevier Science Ltd. All rights reserved.