Stereospecificity in Intramolecular Photoredox Reactions of Naphthoquinones: Enantioselective Total Synthesis of (-)-Spiroxin C

Stereospecificity in Intramolecular Photoredox Reactions of Naphthoquinones: Enantioselective Total Synthesis of (-)-Spiroxin C
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DOI:
10.1002/anie.201705562
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发表时间:
2017-09-11
影响因子:
16.6
通讯作者:
Suzuki, Keisuke
Suzuki, Keisuke
中科院分区:
化学1区
文献类型:
--
作者:
Ando, Yoshio;Hanaki, Atsuko;Suzuki, Keisuke

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发现萘醌衍生物的分子内光氧化还原反应以立体定向的方式进行。该方法为(-)-螺环辛C的立体选择性全合成奠定了基础。
Intramolecular photoredox reactions of naphthoquinone derivatives were found to proceed in a stereospecific manner. This method was used as a basis for the enantioselective total synthesis of (-)-spiroxin C.