Effects of Boundaries on Pattern Formation: Catalytic Oxidation of CO on Platinum

Effects of Boundaries on Pattern Formation: Catalytic Oxidation of CO on Platinum
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边界对图案形成的影响:CO 对铂的催化氧化

DOI:
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发表时间:
1994
期刊:
影响因子:
56.9
通讯作者:
G. Ertl
G. Ertl
中科院分区:
综合性期刊1区
文献类型:
--
作者:
M. Graham;I. Kevrekidis;K. Asakura;J. Lauterbach;K. Krischer;H. Rotermund;G. Ertl

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研究了一氧化碳在铂表面上催化氧化时,界面对图形形成的影响。光刻被用来创建微观反应域多晶箔和单晶铂(110)表面与惰性钛覆盖层。某些域的几何形状产生的图案,没有观察到的未经处理的催化剂,并带来光的表面机制,没有类似的均匀的反应扩散系统。
The effect of boundaries on pattern formation was studied for the catalytic oxidation of carbon monoxide on platinum surfaces. Photolithography was used to create microscopic reacting domains on polycrystalline foils and single-crystal platinum (110) surfaces with inert titanium overlayers. Certain domain geometries give rise to patterns that have not been observed on the untreated catalyst and bring to light surface mechanisms that have no analog in homogeneous reaction-diffusion systems.