Neutron crystal structure analysis of stilbazolium derivatives for terahertz-wave generation
Neutron crystal structure analysis of stilbazolium derivatives for terahertz-wave generation
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用于产生太赫兹波的芪唑衍生物的中子晶体结构分析
DOI：
10.1039/c5ce00107b
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发表时间：
2015
期刊：
影响因子：
3.1
通讯作者：
and Toru Ishigaki
中科院分区：
文献类型：
--
作者：
Takeshi Matsukawa;Yukihiko Yoshida;Akinori Hoshikawa;Shuji Okada;and Toru Ishigaki
通过中子衍射测定了芪唑鎓衍生物的精制晶体结构。当苯磺酸盐抗衡阴离子的4位原子较大时，阳离子和阴离子之间的原子间距离增加。 4-卤代苯磺酸芪唑鎓衍生物在太赫兹区域的吸收系数变低。
The refined crystal structure of stilbazolium derivatives was determined by neutron diffraction. The interatomic distances between the cation and the anion increased when the 4-position of the benzenesulfonate counteranion had a larger atom. The absorption coefficients of the 4-halobenzenesulfonate stilbazolium derivatives in the THz region became lower.