A trinuclear manganese(II) complex of 2-acetyl-5-methoxyphenol
A trinuclear manganese(II) complex of 2-acetyl-5-methoxyphenol
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2-乙酰基-5-甲氧基苯酚的三核锰(II)配合物
DOI：
10.1107/s1600536806029278
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发表时间：
2006
期刊：
影响因子：
--
通讯作者：
Xilan Hu
中科院分区：
文献类型：
--
作者：
Xingyou Xu;Tongyu Xu;Shao;Da‐qi Wang;Xilan Hu
标题化合物[Mn_3（C_9H_6 O_3）_6]中，三个Mn Ⅱ原子通过丹皮酚阴离子的去质子化羟基线性连接。一个Mn原子位于反转中心，并与六个羟基O原子配位，位于一般位置的Mn原子与三个羟基O和三个乙酰基O原子配位。在三核分子中，Mn/Mn有一个3.0464（8）A的短分离.
In the title centrosymmetric compound, hexakis(μ-2-acetyl-5-methoxyphenolato)trimanganese(II), [Mn3(C9H6O3)6], three MnII atoms are linearly linked by deprotonated hydroxyl groups of paeonol anions. One Mn atom is located on an inversion center and is coordinated by six hydroxy O atoms, and the Mn atom located on a general position is coordinated by three hydroxy O and three acetyl O atoms. Within the trinuclear molecule, there is a short Mn⋯Mn separation of 3.0464 (8) A.