Lithium borohydride-melamine complex as a promising material for chemical hydrogen storage

Lithium borohydride-melamine complex as a promising material for chemical hydrogen storage
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硼氢化锂-三聚氰胺复合物作为一种有前景的化学储氢材料

DOI:
10.1016/j.jallcom.2012.09.100
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发表时间:
2013-03
影响因子:
6.2
通讯作者:
Chen Ping
Chen Ping
中科院分区:
材料科学2区
文献类型:
--
作者:
Liu Lin;Hu Daqiang;He Teng;Zhang Yao;Wu Guotao;Chu Hailiang;Wang Peikun;Xiong Zhitao;Chen Ping

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A complex hydride, 3LiBH4·C3N6H6, crystallizing in monoclinic structure with lattice parameters of a=17.4701Å, b=17.6332Å, c=4.1749Å, β=99.7453° and V=1267.54Å3, was synthesized by solid reaction between LiBH4and C3N6H6. 3LiBH4·C3N6H6starts to evolve hydrogen at 100°C, which is 190°C lower than that of pristine LiBH4. Combination of protic hydrogen of [BH4]−and hydridic hydrogen of NH in 3LiBH4·C3N6H6may greatly improve the dehydrogenation properties, and totally 7.83wt.% H2can be released from 3LiBH4·C3N6H6in the temperature range of 100–340°C.
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