Radical reactions of didehydroarenes with a 1,4-relationship
Radical reactions of didehydroarenes with a 1,4-relationship
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DOI：
10.1021/ja0360079
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发表时间：
2003-11-26
影响因子：
15
通讯作者：
Kenttämaa, HI
中科院分区：
文献类型：
--
作者：
Amegayibor, FS;Nash, JJ;Kenttämaa, HI
具有1,4关系的二脱氢芳烃的气相自由基反应性研究表明，电子效应（由于单线态-三重态分裂）可以被极性效应抵消。
A gas-phase study of the radical reactivities of didehydroarenes with a 1,4-relationship reveals that electronic effects (due to singlet−triplet state splittings) can be offset by polar effects.