DETECTION OF AN INTERMEDIATE TERNARY COMPLEX IN THE REDUCTION OF p-BENZOQUINONE DERIVATIVES BY AN NADH MODEL COMPOUND IN THE PRESENCE OF Mg2+ ION
DETECTION OF AN INTERMEDIATE TERNARY COMPLEX IN THE REDUCTION OF p-BENZOQUINONE DERIVATIVES BY AN NADH MODEL COMPOUND IN THE PRESENCE OF Mg2+ ION
复制标题
Mg2离子存在下NADH模型化合物还原对苯醌衍生物中中间三元配合物的检测
DOI：
10.1246/cl.1983.1755
复制
发表时间：
1983
影响因子：
1.6
通讯作者：
Toshio Tanaka
中科院分区：
文献类型：
--
作者：
S. Fukuzumi;Nobuaki Nishizawa;Toshio Tanaka
在Mg ~（2+）存在的乙腈溶液中，当NADH模型化合物还原对苯醌衍生物时，观察到了由NADH模型化合物-Mg ~（2+）络合物到对苯醌衍生物的电荷转移（CT）跃迁引起的一个瞬态CT带。的三元复合物中的还原由NADH模型化合物的作用的报告。
A transient charge-transfer (CT) band of a ternary complex due to the CT transition from an NADH model compound — Mg2+ ion complex to a p-benzoquinone derivative was observed in the reduction of a p-benzoquinone derivative by an NADH model compound in the presence of Mg2+ ion in acetonitrile. The role of the ternary complex in the reduction by an NADH model compound is reported.