CC Hydrogenations with Iron Group Metal Catalysts
CC Hydrogenations with Iron Group Metal Catalysts
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DOI：
10.1002/9783527699087.ch5
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发表时间：
2018-12
期刊：
影响因子：
--
通讯作者：
Tim N. Gieshoff;A. J. V. Wangelin
中科院分区：
文献类型：
--
作者：
Tim N. Gieshoff;A. J. V. Wangelin
在过去的十年里，由于发展了明确的贱金属络合物，均相贱金属催化的C--C加氢领域蓬勃发展。通过合理的配体设计，实现了铁族金属络合物新的二氢活化机理，并将其应用于烯烃和烯烃的加氢反应。本章旨在总结基于铁、钴和镍的均相C--C加氢催化剂的最新进展。
In the past decade, the field of homogeneous base‐metal‐catalyzed CC hydrogenations flourished because of the development of well‐defined base–metal complexes. Through a rational ligand design, new dihydrogen activation mechanisms were enabled with iron group metal complexes and applied in the hydrogenation of alkenes and alkynes. This chapter aims to summarize the latest advances in homogeneous CC hydrogenation catalysis based on iron, cobalt, and nickel.