An X-Ray Diffraction Study of the Structure of Hydrated Copper(II) Ion in a Copper(II) Perchlorate Solution
An X-Ray Diffraction Study of the Structure of Hydrated Copper(II) Ion in a Copper(II) Perchlorate Solution
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高氯酸铜(II)溶液中水合铜(II)离子结构的X射线衍射研究
DOI：
10.1246/bcsj.47.2197
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发表时间：
1974
影响因子：
4
通讯作者：
M. Maeda
中科院分区：
文献类型：
--
作者：
H. Ohtaki;M. Maeda
通过 3.55 M 高氯酸铜 (II) 溶液的 X 射线衍射测定水合铜 (II) 离子的结构。径向分布曲线表明铜(II)离子具有由六个水分子组成的扭曲八面体结构。四个水分子占据八面体的赤道位置，距 Cu(II) 离子 1.94±0.02 A，另外两个水分子位于轴向位置，距中心离子 2.43±0.03 A。
The structure of hydrated copper(II) ion was determined by means of the X-ray diffraction of a 3.55 M copper(II) perchlorate solution. The radial distribution curve showed that the copper(II) ion has a distorted octahedral structure with six water molecules. Four water molecules occupy the equatorial sites of the octahedron at a distance of 1.94±0.02 A from the Cu(II) ion and the other two water molecules at the axial sites are 2.43±0.03 A distant from the central ion.