Effect of functional group of ferrocene redox substance on the transport properties of newly designed ion exchange membrane prepared from polymer gel
Effect of functional group of ferrocene redox substance on the transport properties of newly designed ion exchange membrane prepared from polymer gel
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二茂铁氧化还原物质官能团对新型聚合物凝胶离子交换膜传输性能的影响
DOI：
10.1002/app.27164
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发表时间：
2008
影响因子：
3
通讯作者：
A. Yamauchi
中科院分区：
文献类型：
--
作者：
A. M. Sayed;Shinya Yamasaki;A. Yamauchi
介绍了一种新型阳离子交换聚合物膜和一种阴离子交换聚合物膜，并对这两种聚合物膜的传质性能进行了研究。这些聚合物膜与二茂铁氧化还原衍生物接触的传输性能估计通过使用电化学技术，如循环伏安法，计时电位法，计时电流法技术，分别。所使用的具有不同官能团的二茂铁氧化还原物质是（二茂铁甲基）三甲基碘化铵FcMA、二茂铁二甲醇FcDM和二茂铁羧酸FcCA。结果表明，膜的性能取决于聚合物凝胶含量、阴离子交换聚合物中心（20 wt %和50 wt %）或阳离子交换聚合物中心（20 wt %和50 wt %）以及阳离子和阴离子交换聚合物中心官能团的效率。© 2007 Wiley Periodicals，Inc.应用聚合物科学杂志，2008年
A different newly designed cationic exchange polymer membrane and anionic exchange polymer membrane were introduced, and also the transport properties of these polymeric membranes were investigated in this study. The transport properties of these polymer membranes in contact with ferrocene redox derivatives were estimated by using electrochemical techniques such as cyclicvoltammetry, chronopotentiometry, and chronoamperometry techniques, respectively. The used ferrocene redox substances, which have different functional groups, were (Ferrocenylmethyl) trimethylamonium iodide, FcMA, Ferrocenedimethanol, FcDM, and Ferrocene carboxylic acid, FcCA. It indicated that the performance of a membrane depended on the content of polymer gel, anionic exchange polymer site (20 wt % and 50 wt %) or cationic polymer exchange site (20 wt % and 50 wt %), and the efficiency of the functional groups of cationic and anionic exchange polymer site as well. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008