The Thermoelectric Properties of Metal-Ammonia Solutions. II. The Thermoelectric Power of Sodium and Potassium Solutions at —78° and the Effect of Added Salt on the Thermoelectric Power of Sodium at —33°
The Thermoelectric Properties of Metal-Ammonia Solutions. II. The Thermoelectric Power of Sodium and Potassium Solutions at —78° and the Effect of Added Salt on the Thermoelectric Power of Sodium at —33°
复制标题
金属-氨溶液的热电性能 II. 钠和钾溶液在 —78° 时的热电势以及添加盐对钠在 —33° 时热电势的影响。
DOI：
10.1021/ja01594a009
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发表时间：
1956
影响因子：
15
通讯作者：
J. F. Dewald
中科院分区：
文献类型：
--
作者：
G. Lepoutre;J. F. Dewald
本文报道了在-78℃的液氨中和-33℃的钠-氯化钠混合溶液中测量钠和钾溶液的温差电势。稀溶液中的结果表明，温差电势对温度和盐浓度的依赖性非常大，对金属离子的性质也有很小但很大的依赖性。
Measurements of the thermoelectric power of sodium and potassium solutions in liquid ammonia at—78 and of mixed sodium-sodium chloride solutions at— 33 are reported. The results in dilute solution show an anomalously large dependence of thermoelectric power on temperature and on concentration of salt, as well as a small but significant dependence on the nature of the metal ion.