Organic Electrode Materials for Rechargeable Lithium Batteries
Organic Electrode Materials for Rechargeable Lithium Batteries
复制标题
可充电锂电池有机电极材料
DOI：
10.1002/aenm.201100795
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发表时间：
2012-07-01
影响因子：
27.8
通讯作者：
Chen, Jun
中科院分区：
文献类型：
--
作者：
Liang, Yanliang;Tao, Zhanliang;Chen, Jun
有机化合物为高能量/功率密度、成本效益、环境友好和功能性可充电锂电池提供了新的可能性。长期以来，它们并没有构成一类重要的电极材料，部分原因是无机插层化合物的巨大成功和快速发展。然而，近年来取得了令人兴奋的进展，使有机电极引起了储能界的注意。本文综述了锂离子二次电池用有机化合物三十年来的研究工作。介绍了有机硫化合物、有机自由基化合物、有机羰基化合物、导电聚合物、非共轭氧化还原聚合物和层状有机化合物等材料的工作原理、发展历史和设计策略。这些材料的电池性能进行了比较，提供了该领域的全面概述，并直接揭示了每类材料的优点/缺点。
Organic compounds offer new possibilities for high energy/power density, cost-effective, environmentally friendly, and functional rechargeable lithium batteries. For a long time, they have not constituted an important class of electrode materials, partly because of the large success and rapid development of inorganic intercalation compounds. In recent years, however, exciting progress has been made, bringing organic electrodes to the attention of the energy storage community. Herein thirty years' research efforts in the field of organic compounds for rechargeable lithium batteries are summarized. The working principles, development history, and design strategies of these materials, including organosulfur compounds, organic free radical compounds, organic carbonyl compounds, conducting polymers, non-conjugated redox polymers, and layered organic compounds are presented. The cell performances of these materials are compared, providing a comprehensive overview of the area, and straightforwardly revealing the advantages/disadvantages of each class of materials.