Ring-opening polymerization of cyclobutane derived from tetracyanoethylene and ethyl vinyl ether with Lewis acids

Ring-opening polymerization of cyclobutane derived from tetracyanoethylene and ethyl vinyl ether with Lewis acids
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四氰乙烯和乙基乙烯基醚与路易斯酸的环丁烷开环聚合

DOI:
10.1002/marc.1993.030141208
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发表时间:
1993
期刊:
影响因子:
--
通讯作者:
Tooru Fujino
Tooru Fujino
中科院分区:
--
文献类型:
--
作者:
T. Yokozawa;Tooru Fujino

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研究了1,1,2,2-四氰-3-乙氧基环丁烷与路易斯酸和质子酸的开环聚合反应。得到了四氰乙烯与乙基乙烯醚的交变共聚物。提出了两性离子反应机理
The ring opening polymerization of 1,1,2,2-tetracyano-3-ethoxycyclobutane with Lewis acids and protonic acids was investigated. The alternating copolymer of tetracyanoethylene with ethyl vinyl ether was obtained. The reaction mechanism was proposed to be zwitterionic