Controlling the passage of light through metal microchannels by nanocoatings of phospholipids.
Controlling the passage of light through metal microchannels by nanocoatings of phospholipids.
复制标题
通过磷脂纳米涂层控制光通过金属微通道。
DOI：
10.1021/jp062201g
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发表时间：
2006
期刊：
影响因子：
--
通讯作者：
Coe,JamesV
中科院分区：
文献类型：
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作者：
Teeters-Kennedy,ShannonM;Rodriguez,KennethR;Rogers,TrishaM;Zomchek,KeithA;Williams,ShaunM;Sudnitsyn,Alexandra;Carter,Lauren;Cherezov,Vadim;Caffrey,Martin;Coe,JamesV
通过具有微通道阵列的金属膜的偏振光的流动由光学活性的磷脂纳米涂层的相位控制，即使涂层不覆盖微通道的开放区域。使用红外线，表面等离子体介导的，非凡的传输的金属微阵列的组件（DPPC磷脂单层/双分子层上的十六烷硫醇单层上的铜或镍涂层的微阵列）的分子细节进行了测定。记录了与文献相比具有极大增强的吸收的红外吸收光谱，并将其用作这些纳米涂层的相、组成和分子几何形状的诊断。这种方法为在狭窄的微空间中进行纳米级构造提供了新的工具，这最终可能对单个微通道有用。
The flow of polarized light through a metal film with an array of microchannels is controlled by the phase of an optically active, phospholipid nanocoating, even though the coating does not cover the open area of the microchannels. The molecular details of the assembly (DPPC phospholipid monolayer/bilayer on a hexadecanethiol monolayer on a copper- or nickel-coated microarray) were determined using the infrared, surface-plasmon-mediated, extraordinary transmission of the metal microarrays. Infrared absorption spectra with greatly enhanced absorptions by comparison to literature were recorded and used as a diagnostic for the phase, composition, and molecular geometry of these nanocoatings. This approach presents new tools for nanoscale construction in constricted microspaces, which may ultimately be useful with individual microchannels.