Recent Advances in the Syntheses of Diazaporphyrins and Their Chalcogen Derivatives
Recent Advances in the Syntheses of Diazaporphyrins and Their Chalcogen Derivatives
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二氮杂卟啉及其硫属衍生物的合成研究新进展
DOI：
10.1039/d3ob00274h
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发表时间：
2023
影响因子：
3.2
通讯作者：
Yoshihiro Matano
中科院分区：
文献类型：
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作者：
Kilingaru I. Shivakumar;Yasuhide Inokuma;Yoshihiro Matano
卟啉类化合物因其独特的颜色、丰富的电化学和光学性质而成为科学领域中极具影响力的功能材料。用氮对卟啉环进行外围修饰是赋予天然和人造卟啉前所未有的功能的一种有吸引力的方法。二氮杂卟啉（DAP）是一类具有两个内消旋氮原子的化合物。DAP表现出与卟啉明显不同的特征氧化还原和光学性质。基于DAP的敏化剂、催化剂和材料的制备和化学功能化在诸如医学科学、有机合成和材料化学的各个领域中获得了显著的关注。本文综述了近年来二氮杂卟啉及其硫属元素衍生物的合成研究进展，包括具有历史意义的实例。
Porphyrins are highly influential functional materials in the field of science owing to their fascinating colors and diverse electrochemical and optical properties. Peripheral modification of porphyrin rings with nitrogen is an attractive approach for imparting unprecedented functions to both natural and artificial pophyrins. Diazaporphyrins (DAPs) are a class of compounds that have two meso-nitrogen atoms. DAPs exhibit characteristic redox and optical properties that differ significantly from those of porphyrins. The preparation and chemical functionalization of DAP-based sensitizers, catalysts, and materials have gained significant attention in various fields such as medical science, organic synthesis, and materials chemistry. This review focuses on recent advances in the synthesis of diazaporphyrins and their chalcogen derivatives, including historically important examples.