LiFePO4/TiO2/Pt composite film used as effective and robust counter electrode for dye sensitized solar cells

LiFePO4/TiO2/Pt composite film used as effective and robust counter electrode for dye sensitized solar cells
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LiFePO4/TiO2/Pt 复合薄膜用作染料敏化太阳能电池有效且坚固的对电极

DOI:
10.1007/s10854-017-7786-5
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发表时间:
2017-09
影响因子:
2.8
通讯作者:
Feng Jiwen
Feng Jiwen
中科院分区:
工程技术4区
文献类型:
--
作者:
Di Yi;Xiao Zhanhai;Chen Bing;Feng Jiwen

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A series of composite films based on LiFePO4/TiO2/Pt were synthesized and used as counter electrodes for dye sensitized solar cells (DSSCs). The composites are characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and Brunauer–Emmett–Teller (BET). These analysis results demonstrate that the crystal structure of LiFePO4in composite is not changed, and the prepared LiFePO4/TiO2/Pt composite films hold a rough surface and porous structure which provide more catalytic activity sites for I3−reduction and more space for I−/I3−diffusion. The DSSC based on LiFePO4/TiO2/Pt composite CEs shows a high power conversion efficiency of 6.23% at a low Pt dosage of 2%, comparable to the conventional magnetron sputtering Pt CE (6.31%). The electrochemical analysis reveals that the presented composite CEs have good electrocatalytic activity and low charge transfer resistance. Furthermore, the DSSCs based on LiFePO4/TiO2/Pt composite CE exhibit high stability under the continuous tests condition and electrolyte soaking. The results suggest that this LiFePO4-based composite film could be a perspective electrode for practical application of DSSCs and it maybe provide a potential for further research about photo-charging lithium-ion batteries.
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