catena-Poly[[diaqua-nickel(II)]-μ-7-oxabicyclo-[2.2.1]heptane-2,3-di-carboxyl-ato].

catena-Poly[[diaqua-nickel(II)]-μ-7-oxabicyclo-[2.2.1]heptane-2,3-di-carboxyl-ato].
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链式聚[[diaqua-镍(II)]-μ-7-氧杂双环-[2.2.1]庚烷-2,3-二羧基-ato]。

DOI:
10.1107/s1600536809021771
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发表时间:
2009
期刊:
Acta crystallographica. Section E, Structure reports online
影响因子:
--
通讯作者:
Lin,Qiu-Yue
Lin,Qiu-Yue
中科院分区:
--
文献类型:
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作者:
Wang,Yun-Yun;Hu,Rui-Ding;Zhu,Wen-Zhong;Lin,Qiu-Yue

文献摘要

相似文献

在标题化合物[Ni(C8H8O5)(H2O)2]n的晶体结构中,NiII离子处于Jahn-Teller扭曲的八面体配位环境中,与来自水分子的两个O原子、双环庚烷单元的桥联O原子、来自不同羧基的两个羧基O原子和来自对称相关桥联配体的一个羧基O原子结合。晶体结构是由平行于BC平面传播的层组成的。
In the crystal structure of the title compound, [Ni(C8H8O5)(H2O)2]n, the NiII cation is in a Jahn–Teller-distorted octahedral coordination environment binding to two O atoms from water molecules, the bridging O atom of the bicycloheptane unit, two carboxylate O atoms from different carboxylate groups and one carboxylate O atom from a symmetry-related bridging ligand. The crystal structure is made up from layers propagating parallel to the bc plane.