catena-Poly[[diaqua-nickel(II)]-μ-7-oxabicyclo-[2.2.1]heptane-2,3-di-carboxyl-ato].
catena-Poly[[diaqua-nickel(II)]-μ-7-oxabicyclo-[2.2.1]heptane-2,3-di-carboxyl-ato].
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链式聚[[diaqua-镍(II)]-μ-7-氧杂双环-[2.2.1]庚烷-2,3-二羧基-ato]。
DOI:
10.1107/s1600536809021771
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发表时间:
2009
期刊:
影响因子:
--
通讯作者:
Lin,Qiu-Yue
中科院分区:
文献类型:
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作者:
Wang,Yun-Yun;Hu,Rui-Ding;Zhu,Wen-Zhong;Lin,Qiu-Yue
In the crystal structure of the title compound, [Ni(C8H8O5)(H2O)2]n, the NiII cation is in a Jahn–Teller-distorted octahedral coordination environment binding to two O atoms from water molecules, the bridging O atom of the bicycloheptane unit, two carboxylate O atoms from different carboxylate groups and one carboxylate O atom from a symmetry-related bridging ligand. The crystal structure is made up from layers propagating parallel to the bc plane.