Keeping Reactions Under Quantum Control
Keeping Reactions Under Quantum Control
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将反应置于量子控制之下
DOI：
10.1126/science.1060883
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发表时间：
2001
期刊：
影响因子：
56.9
通讯作者：
A. Castleman
中科院分区：
文献类型：
--
作者：
S. M. Hurley;A. Castleman
长期以来，人们一直认为反应可以用激光控制，但复杂系统的成功必须等到超快激光预示着飞秒化学领域。在他们的观点中，[Hurley和Castleman][1]强调了[ Levis等人]的报告。[2]他们证明了强场激光脉冲可以用来控制解离重排反应。键不仅选择性地断裂，而且选择性地形成。
[1]：http://www.sciencemag.org/cgi/content/full/292/5517/648
[2]：http://www.sciencemag.org/cgi/content/short/292/5517/709
It has long been proposed that reactions can be controlled with lasers, but success with complex systems had to wait until ultrafast lasers heralded the field of femtosecond chemistry. In their Perspective, [Hurley and Castleman][1] highlight the report of [ Levis et al .][2], who show that strong-field laser pulses can be used to control a dissociative rearrangement reaction. Bonds are not only selectively broken but also selectively formed.
[1]: http://www.sciencemag.org/cgi/content/full/292/5517/648
[2]: http://www.sciencemag.org/cgi/content/short/292/5517/709