Ru-Catalyzed Highly Diastereoselective Hydrogenation of N-tert-butylsulfinyl Ketimino Esters
Ru-Catalyzed Highly Diastereoselective Hydrogenation of N-tert-butylsulfinyl Ketimino Esters
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DOI:
10.1039/c7ob01329a
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发表时间:
2017
期刊:
影响因子:
--
通讯作者:
tang weijun
中科院分区:
文献类型:
--
作者:
Wei qiaoling;tang weijun
A ruthenium pincer catalyst has been shown to be highly efficient for the hydrogenation of a wide range ofα-ketimino esters derived from α-keto esters and chiral 2-methylpropane-2-sulfinamide, affording chiral aryl glycine derivatives with high yields and diasteroselecvitities (20 examples, d.r. values up to 99: 1).