Kinetics of the reaction of CF3O2radicals with O(3P) atoms
Kinetics of the reaction of CF3O2radicals with O(3P) atoms
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DOI：
10.1039/a701933e
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发表时间：
1997
期刊：
影响因子：
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通讯作者：
P. Biggs;C. E. Canosa-mas;D. Shallcross;A. Vipond;R. Wayne
中科院分区：
文献类型：
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作者：
P. Biggs;C. E. Canosa-mas;D. Shallcross;A. Vipond;R. Wayne
A discharge fast-flow tube equipped with laser-induced fluorescence detection for NO 2 , produced from the titration of CF 3 O 2 with NO, and chemiluminescence detection for O( 3 P), was employed to determine the rate constant for the reaction CF 3 O 2 +O( 3 P)→products, at T=296±1 K and P=ca. 2 Torr. The rate constant was found to be (6.3±1.0)×10 -11 cm 3 molecule -1 s -1 . Some implications of the results for atmospheric chemistry are discussed.
