PRIMARY AND SECONDARY OXYGEN-INDUCED C1S BINDING-ENERGY SHIFTS IN X-RAY PHOTOELECTRON-SPECTROSCOPY OF POLYMERS
PRIMARY AND SECONDARY OXYGEN-INDUCED C1S BINDING-ENERGY SHIFTS IN X-RAY PHOTOELECTRON-SPECTROSCOPY OF POLYMERS
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DOI：
10.1021/ac00039a018
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发表时间：
1992-08-01
影响因子：
7.4
通讯作者：
BEAMSON, G
中科院分区：
文献类型：
--
作者：
BRIGGS, D;BEAMSON, G
共43只含有C，H和O的聚合物进行了研究，使用的X射线光电子能谱仪能够提供最高的能量分辨率到目前为止。其主要目的是重新调查的C1 s结合能位移的氧功能，并首次系统地调查二次（β）位移。此外，这个大的数据集已经揭示了振动精细结构对C1 s组分的线宽/形状的影响，以及抖动/抖动（在来自C=O基团的光电发射中）对C1 s组分强度的非化学计量的影响。
A total of 43 polymers containing only C, H, and O have been studied using an X-ray photoelectron spectroscopy instrument capable of the highest energy resolution available to date. The primary aim was to reinvestigate the C1s binding energy shifts for oxygen functionalities and to systematically investigate secondary (beta) shifts for the first time. In addition, this large data set has revealed the effects of vibrational fine structure on C1s component line width/shape and the effects of shake-up/shake-off (in photoemission from C=O groups) on nonstoichiometry of C1s component intensities.