External‐Ligand‐Free Aerobic Oxidation of N‐ and C‐Containing Cyclic Systems under Pd‐Catalyzed Conditions
External‐Ligand‐Free Aerobic Oxidation of N‐ and C‐Containing Cyclic Systems under Pd‐Catalyzed Conditions
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DOI：
10.1002/ajoc.201600465
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发表时间：
2017
影响因子：
2.7
通讯作者：
Yue Wang;Caifeng Li;Jianhui Huang
中科院分区：
文献类型：
--
作者：
Yue Wang;Caifeng Li;Jianhui Huang
本文报道了在Pd催化剂的存在下，利用易于获得的无机碱（KOtBu）对含N和c的杂环进行方便的好氧氧化。一系列含n的杂芳香族化合物以及一些苯胺类化合物已经成功地制备了。这种具有成本效益的合成为合成各种其他有用的杂芳烃化合物开辟了潜在的应用途径。
A convenient aerobic oxidation of N- and C-containing heterocycles using a readily available inorganic base (KOtBu) in the presence of a Pd catalyst is reported. A range of N-containing heteroaromatic compounds as well as a number of anilines have been successfully prepared in good yields. This cost-efficient synthesis has opened the pathway toward a potential application for the synthesis of a variety of other useful heteroaromatic compounds.