Donor–acceptor origin of fullerene C60 dimerization
Donor–acceptor origin of fullerene C60 dimerization
复制标题
富勒烯C60二聚化的供体-受体起源
DOI：
10.1002/qua.21420
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发表时间：
2007
影响因子：
2.2
通讯作者：
E. Sheka
中科院分区：
文献类型：
--
作者：
E. Sheka
富勒烯二聚化被认为是单体分子之间供体-受体相互作用的结果，这对于 C60+C60 二元系统非常重要。二聚化是由基态能量项的双阱结构提供的。分析该术语的特征，通过不同起始分子间距离的量子化学计算证明，提出了物理（光激发、热、高压、等离子体、电子束和电场）和化学（碱金属加合物 AC60）刺激二聚过程的机制。 © 2007 Wiley periodicals, Inc. Int J Quantum Chem，2007
The fullerene dimerization is considered as a consequence of donor–acceptor interaction between monomer molecules which is significant for C60+C60 binary system. The dimerization is provided by a two-well structure of the ground state energy term. Analyzing characteristics of the term, proven by quantum–chemical calculations at different starting intermolecular distances, mechanisms of both physically (photoexcitation, thermal, high pressure, plasma, electron beam, and electric field) and chemically (alkali-metal adducts AC60) stimulated dimerization processes are suggested. © 2007 Wiley Periodicals, Inc. Int J Quantum Chem, 2007
卟啉-富勒烯二元体中电场对光致电子转移速率的加速和减速
DOI：
--
发表时间：
2003
期刊：
Chem.Phys.Lett. 368
影响因子：
--
作者：
N.Ohta;S.Mikami;Y.Iwaki;M.Tsushima;H.Imahori;K.Tamaki;Y.Sakata;S.Fukuzumi
通讯作者：
S.Fukuzumi