Selective Aerobic Oxidation of Alcohols to Aldehydes, Carboxylic Acids, and Imines Catalyzed by a Ag-NHC Complex
Selective Aerobic Oxidation of Alcohols to Aldehydes, Carboxylic Acids, and Imines Catalyzed by a Ag-NHC Complex
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DOI：
10.1021/ol501353q
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发表时间：
2014-07-04
期刊：
影响因子：
5.2
通讯作者：
Jiang, Biao
中科院分区：
文献类型：
--
作者：
Han, Lei;Xing, Ping;Jiang, Biao
银 NHC 催化剂已开发用于在干燥空气下、BnMe3NOH 或 KOH 存在下将醇选择性氧化为醛或羧酸。有氧氧化条件温和，收率优良。进一步的串联催化使得亚胺的一锅合成具有优异的收率。仅需要 0.1 mol% 的催化剂。
Silver NHC catalysts have been developed for the selective oxidation of alcohols to aldehydes or carboxylic acids in the presence of BnMe3NOH or KOH under dry air. The aerobic oxidation conditions are mild, and the yield is excellent. Further tandem catalysis enables the one-pot synthesis of imines in excellent yield. Only 0.1 mol % of the catalyst is required.