Nickel catalyzed α-arylation of ketones with aryltrimethylammonium triflates
Nickel catalyzed α-arylation of ketones with aryltrimethylammonium triflates
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镍催化酮与芳基三甲基三氟甲磺酸铵的 α-芳基化
DOI：
10.1039/c6ob01299j
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发表时间：
2016-01-01
影响因子：
3.2
通讯作者：
Wang, Zhong-Xia
中科院分区：
文献类型：
--
作者：
Li, Jing;Wang, Zhong-Xia
已经完成了镍催化的酮的α-芳基化反应，包括芳香族C-N断裂。在Ni（COD）（2）、IPr中心点HCl和LiOBut存在下，实现了芳香酮与各种芳基三甲基三氟甲磺酸铵的分子间偶联，以合理到优异的产率得到α-芳基化酮。
Nickel-catalyzed alpha-arylation of ketones involving aromatic C-N cleavage has been accomplished. Inter-molecular coupling of aromatic ketones with a variety of aryltrimethylammonium triflates was achieved in the presence of Ni(COD)(2), IPr center dot HCl, and LiOBut, giving alpha-arylated ketones in reasonable to excellent yields.