Decoupling optical and electronic optimization of organic solar cells using high-performance temperature-stable TiO2/Ag/TiO2 electrodes

Decoupling optical and electronic optimization of organic solar cells using high-performance temperature-stable TiO2/Ag/TiO2 electrodes
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DOI:
10.1063/1.4933414
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发表时间:
2015-10-01
期刊:
影响因子:
6.1
通讯作者:
Schmidt-Mende, Lukas
Schmidt-Mende, Lukas
中科院分区:
材料科学2区
文献类型:
--
作者:
Kim, Kwang-Dae;Pfadler, Thomas;Schmidt-Mende, Lukas

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成功制备了具有上级热稳定性的TiO 2/Ag/TiO 2(达特)多层膜作为氧化铟锡(ITO)替代物的电极。该电极允许通过改变夹层结构中的层的厚度来直接调谐光学腔模式朝向最大化光电流产生。这使得能够针对不同的有机薄膜光致发光器件定制优化透明电极,而不改变它们的电光性质。采用我们的达特多层膜的有机光伏器件显示出比ITO参考器件提高约12%的性能,PTB 7:PC 71 BM器件的功率转换效率(PCE)高达8.7%。(C)2015年作者。
An electrode structured with a TiO2/Ag/TiO2 (TAT) multilayer as indium tin oxide (ITO) replacement with a superior thermal stability has been successfully fabricated. This electrode allows to directly tune the optical cavity mode towards maximized photocurrent generation by varying the thickness of the layers in the sandwich structure. This enables tailored optimization of the transparent electrode for different organic thin film photovoltaics without alteration of their electro-optical properties. Organic photovoltaic featuring our TAT multilayer shows an improvement of similar to 12% over the ITO reference and allows power conversion efficiencies (PCEs) up to 8.7% in PTB7:PC71BM devices. (C) 2015 Author(s).