Promoting dynamic adsorption of Pb2+ in a single pass flow using fibrous nano-TiO2/cellulose membranes

Promoting dynamic adsorption of Pb2+ in a single pass flow using fibrous nano-TiO2/cellulose membranes
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使用纤维状纳米 TiO2/纤维素膜促进单程流中 Pb2 的动态吸附

DOI:
10.1016/j.cej.2015.08.068
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发表时间:
2016
影响因子:
15.1
通讯作者:
Chuanfang Yang
Chuanfang Yang
中科院分区:
工程技术1区
文献类型:
--
作者:
Yanxiang Li;Lei Li;Lixia Cao;Chuanfang Yang

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A variety of nano-TiO2/cellulose composite fibers (TiO2/CF) were synthesized via bothin situgrowing rutile TiO2nanocrystals and electrostatic self-assembly of commercial nano rutile TiO2particles onto cellulose fibers. These fibers were then processed into fibrous membrane beds by wet-laid technique. Dynamic adsorption of lead (Pb2+) was subsequently carried out by pumping the feed solution through the bed in a single-pass flow mode. The influence of various parameters including flow rate, bed height and bed stacking pattern on bed breakthrough behavior was investigated. It was found that thein situ-TiO2/CF bed outperformed others; its loading capacity of Pb2+was 13 times that of pure CF bed, and 9 times that of the self-assembled TiO2/cellulose bed prior to 10% breakthrough. The dynamic adsorption behavior of thein situ-TiO2/CF bed was better predicted by Dose–Response model among other models tested. The bed was also selective for Pb2+over Ca2+, and was readily regenerable when eluted with 0.1 M HCl solution for repeated use. The outstanding performance of thein situ-TiO2/CF bed was a result of larger fiber adsorption capacity and faster adsorption kinetics compared with the other beds having similar geometric bed structure.
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