Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes.
Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes.
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DOI：
10.1039/c1cc11765c
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发表时间：
2011-05
影响因子：
4.9
通讯作者：
Cheng‐Pan Zhang;Zong-Ling Wang;Qing‐Yun Chen;Chun-Tao Zhang;Yucheng Gu;Ji-Chang Xiao
中科院分区：
文献类型：
--
作者：
Cheng‐Pan Zhang;Zong-Ling Wang;Qing‐Yun Chen;Chun-Tao Zhang;Yucheng Gu;Ji-Chang Xiao
S-（三氟甲基）二苯基锍三氟甲磺酸盐与Na（2）S（2）O（4）或HOCH（2）SO（2）Na在适当条件下反应生成CF（3）自由基，无需进一步还原。在此基础上，成功地发展了α-三氟甲基酮的合成方法。
The CF(3) radical was generated from the reaction of S-(trifluoromethyl)diphenylsulfonium triflate with Na(2)S(2)O(4) or HOCH(2)SO(2)Na under suitable conditions without further reduction. Based on this, a method for the synthesis of α-trifluoromethylated ketones has been successfully developed.