A thermodynamic assessment of the Co-Sn system

A thermodynamic assessment of the Co-Sn system
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DOI:
10.1016/j.calphad.2004.08.001
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发表时间:
2004-06-01
影响因子:
2.4
通讯作者:
Ishida, K
Ishida, K
中科院分区:
材料科学2区
文献类型:
--
作者:
Jiang, M;Sato, J;Ishida, K

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对 Co-Sn 体系的相图和热力学性质进行了关键评估和热力学建模。人们更加关注再现液态 Co-Sn 的热力学性质,包括混合焓中明显的温度依赖性以及实验观察到的成分随符号变化的活性。四子晶格模型已用于描述 betaCo(3)Sn(2) 和 alphaCo(3)Sn(2) 之间的有序现象。 (C) 2004 Elsevier Ltd. 保留所有权利。
A critical evaluation and thermodynamic modeling of the phase diagram and thermodynamic properties have been presented for the Co-Sn system. More attention has been paid to reproduce the thermodynamic properties of the liquid Co-Sn, including the appreciable temperature dependence in the mixing enthalpy and the sign-variable activity with composition observed by experiments. A four-sublattice model has been used to describe the ordering phenomenon between betaCo(3)Sn(2) and alphaCo(3)Sn(2). (C) 2004 Elsevier Ltd. All rights reserved.