Synthesis, Characterization, and Structural Investigation of the First Bioinorganic Titanocene(IV) .alpha.-Amino Acid Complexes Prepared from the Antitumor Agent Titanocene Dichloride
Synthesis, Characterization, and Structural Investigation of the First Bioinorganic Titanocene(IV) .alpha.-Amino Acid Complexes Prepared from the Antitumor Agent Titanocene Dichloride
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DOI：
10.1021/om00021a040
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发表时间：
1994-09
期刊：
影响因子：
2.8
通讯作者：
T. Klapoetke;H. Koepf;I. Tornieporth-Oetting;P. White
中科院分区：
文献类型：
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作者：
T. Klapoetke;H. Koepf;I. Tornieporth-Oetting;P. White
2257.5（4）A3，且Z= 4。通过X射线分析和振动光谱法确定，这些化合物代表了非常罕见的物种，其中氨基酸仅通过羧基配位。通过化学分析（C/H/N/Cl）、NMR（14/15 N）、质谱（EI; 3，另外通过DCI）、红外和拉曼光谱表征了所有配合物。
2257.5 (4) A3, and Z= 4. It was established by X-ray analysis and vibrational spectroscopy that these compounds represent examples of very rare species in which the amino acids coordinate solely through the carboxylato group. All complexes have been characterized by chemical analyses (C/H/N/Cl), NMR (, 14/15N), mass (El; 3 in addition by DCI), infrared, and Raman spectroscopy.