Molecular folding screen: folding and unfolding of 1,8-anthrylene-ethynylene oligomers by photochemical cycloaddition and thermal cycloreversion.
Molecular folding screen: folding and unfolding of 1,8-anthrylene-ethynylene oligomers by photochemical cycloaddition and thermal cycloreversion.
复制标题
DOI：
10.1039/b717496a
复制
发表时间：
2008-03
影响因子：
4.9
通讯作者：
S. Toyota;Makoto Kuga;A. Takatsu;M. Goichi;T. Iwanaga
中科院分区：
文献类型：
--
作者：
S. Toyota;Makoto Kuga;A. Takatsu;M. Goichi;T. Iwanaga
由蒽板和乙炔连接体组成的分子折叠屏通过[4 + 4]光环加成立体选择性地折叠成之字形，并通过热环回复展开。
Molecular folding screens consisting of anthracene plates and acetylene linkers stereoselectively fold into a zigzag form by [4 + 4]photocycloaddition, and unfold by thermal cycloreversion.