Mechanism of ruthenium-catalyzed hydrogen transfer reactions.: Evidence for a stepwise transfer of CH and NH hydrogens from an amine to a (cyclopentadienone) ruthenium complex
Mechanism of ruthenium-catalyzed hydrogen transfer reactions.: Evidence for a stepwise transfer of CH and NH hydrogens from an amine to a (cyclopentadienone) ruthenium complex
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DOI：
10.1039/b303258b
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发表时间：
2003-01-01
影响因子：
4.9
通讯作者：
Bäckvall, JE
中科院分区：
文献类型：
--
作者：
Éll, AH;Johnson, JB;Bäckvall, JE
Kinetic deuterium isotope effects and racemization studies indicate that dehydrogenation of an amine by a (cyclopentadienone) ruthenium complex occurs via a slow beta-hydride elimination of coordinated amine followed by a proton transfer from nitrogen to carbonyl oxygen.
