New frontiers in asymmetric catalysis
New frontiers in asymmetric catalysis
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DOI：
10.1002/0470098007
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发表时间：
2007-04
期刊：
影响因子：
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通讯作者：
K. Mikami;M. Lautens
中科院分区：
文献类型：
--
作者：
K. Mikami;M. Lautens
前言。贡献者。1催化不对称还原的配体设计（Takeshi Ohkuma, Masato Kitamura, Ryoji Noyori） 1.1简介。1.2烯烃的加氢。1.3酮的还原。1.4亚胺的还原。参考文献：2氧化配体设计（Tohru Yamada） 2.1简介2.2非功能化烯烃的催化对映选择性环氧化2.3金属催化Baeyer-Villiger氧化2.4醇氧化过程中的光学分辨2.5 2-萘酚的催化对映选择性氧化偶联2.6结束语。参考文献3 C-C键形成的配体设计（Ryo Shintani和Tamio Hayashi）。3.1简介。3.2 1,4加成反应及相关反应。3.3交叉偶联反应。参考文献4小分子（CO， HCN， RNC和CO2）的活化（Kyoko Nozaki）。4.1简介。4.2烯烃的不对称氢甲酰化。4.3不对称碳氢羟基化及相关反应。4.4碳-碳多键与CO形成不对称酮。4.5烯烃的不对称氢氰化。4.6氰化物和异氰化物与醛或亚胺的不对称加成。4.7二氧化碳的不对称加成。4.8结论与展望。参考文献。5基于催化活化CH键和CC键的不对称合成（李志平、李朝军）5.1简介。5.2活化C-H键的不对称合成。5.3活化C-C键的不对称合成。5.4结论与展望。致谢。参考文献6复分解反应的最新进展（Miwako Mori）。6.1简介。6.2烯烃分解。6.3炔分解。6.4炔分解。6.5结论参考文献。7不对称催化中的非线性效应（Henri B. Kagan） 7.1简介。7.2对映体混合物的性质。7.3不对称催化中的非线性效应。7.4反应的主要类别。7.5不对称扩增。7.6当前趋势。7.7结论。鸣谢。外消旋催化剂的不对称活化和失活（Kohsuke Aikawa, Kohsuke Mikami）。8.1简介。8.2消旋催化。8.2.1不对称失活。8.3未来展望。9生物分子手性扩增的不对称自催化及手性均匀性的起源（Kenso Soai, Tsuneomi Kawasaki, and Itaru Sato）。9.1简介。9.2不对称自催化。9.3不对称自催化对手性的放大。9.4不对称自催化及其在手性起源和放大中的作用。9.5结论。鸣谢。催化不对称脱对称反应的最新进展（Tomislav Rovis）。10.1简介。10.2烯丙基烷基化。10.3环氧化合物和叠氮醚开环。10.4桥接体系开环。10.5烯烃复分解。10.6酰化。10.7不对称去质子化。10.8氧化。10.9环酸酐去对称。10.10杂项。10.11结语。致谢。参考文献11手性有机催化剂的历史与展望（Gerald Lelais和David W. C. MacMillan）。11.1简介。11.2历史背景。11.3氨催化：有机催化中的新概念。11.4烯胺催化：诞生、重生和快速发展。11.5 Bronsted酸催化：氢键激活。11.6相转移催化（PTC）。11.7未来视角。致谢。12手性Bronsted/Lewis酸催化剂（Kazuaki Ishihara和Hisashi Yamamoto）。12.1简介。12.2手性Bronsted酸催化剂。12.3手性Lewis酸催化剂。12.4 Lewis酸-辅助手性Bronsted酸催化剂。12.5结论与展望。参考文献。13手性双功能酸/碱催化剂（柴崎正松和金井元明）13.1介绍。13.2手性布朗斯特碱催化。13.3手性布朗斯特碱—路易斯酸双功能催化。13.4手性布朗斯特碱—路易斯酸双功能催化。13.5手性路易斯碱催化。13.6手性路易斯碱—路易斯酸双功能催化。13.7结论。参考文献和注释。索引。
PREFACE. CONTRIBUTORS. 1 Ligand Design for Catalytic Asymmetric Reduction (Takeshi Ohkuma, Masato Kitamura, and Ryoji Noyori) 1.1 Introduction. 1.2 Hydrogenation of Olefins. 1.3 Reduction of Ketones. 1.4 Reduction of Imines. References. 2 Ligand Design for Oxidation (Tohru Yamada) 2.1 Introduction. 2.2 Catalytic Enantioselective Epoxidation of Unfunctionalized Olefins. 2.3 Enantioselective Metal-Catalyzed Baeyer-Villiger Oxidation. 2.4 Optical Resolution during Oxidation of Alcohols. 2.5 Catalytic Enantioselective Oxidative Coupling of 2-Naphthols. 2.6 Concluding Remarks. References. 3 Ligand Design for C-C Bond Formation (Ryo Shintani and Tamio Hayashi). 3.1 Introduction. 3.2 1,4-Addition and Related Reactions. 3.3 Cross-Coupling Reactions. References. 4 Activation of Small Molecules (CO, HCN, RNC, and CO2) (Kyoko Nozaki). 4.1 Introduction. 4.2 Asymmetric Hydroformylation of Olefins. 4.3 Asymmetric Hydrocarbohydroxylation and Related Reactions. 4.4 Asymmetric Ketone Formation from Carbon-Carbon Multiple Bonds and CO. 4.5 Asymmetric Hydrocyanation of Olefins. 4.6 Asymmetric Addition of Cyanide and Isocyanide to Aldehydes or Imines. 4.7 Asymmetric Addition of Carbon Dioxide. 4.8 Conclusion and Outlook. References. 5 Asymmetric Synthesis Based on Catalytic Activation of CH Bonds and CC Bonds (Zhiping Li and Chao-Jun Li) 5.1 Introduction. 5.2 Asymmetric Synthesis via Activation of C-H Bonds. 5.3 Asymmetric Synthesis via Activation of C-C Bonds. 5.4 Conclusions and Outlook. Acknowledgments. References. 6 Recent Progress in the Metathesis Reaction (Miwako Mori). 6.1 Introduction. 6.2 Olefin Metathesis. 6.3 Enyne Metathesis. 6.4 Alkyne Metathesis. 6.5 Conclusions. References. 7 Nonlinear Effects in Asymmetric Catalysis (Henri B. Kagan) 7.1 Introduction. 7.2 Properties of Enantiomer Mixtures. 7.3 Nonlinear Effect in Asymmetric Catalysis. 7.4 Main Classes of Reactions. 7.5 Asymmetric Amplification. 7.6 Current Trends. 7.7 Conclusion. Acknowledgment. References and Notes. 8 Asymmetric Activation and Deactivation of Racemic Catalysts (Koichi Mikami and Kohsuke Aikawa). 8.1 Introduction. 8.2 Racemic Catalysis. 8.2.1 Asymmetric Deactivation. 8.3 Future Perspectives. References and Notes. 9 Asymmetric Autocatalysis with Amplification of Chirality and Origin of Chiral Homogeneity of Biomolecules (Kenso Soai, Tsuneomi Kawasaki, and Itaru Sato). 9.1 Introduction. 9.2 Asymmetric Autocatalysis. 9.3 Amplification of Chirality by Asymmetric Autocatalysis. 9.4 Asymmetric Autocatalysis and Its Role in the Origin and Amplification of Chirality. 9.5 Conclusions. Acknowledgment. References. 10 Recent Advances in Catalytic Asymmetric Desymmetrization Reactions (Tomislav Rovis). 10.1 Introduction. 10.2 Allylic Alkylation. 10.3 Ring Opening of Epoxides and Aziridines. 10.4 Ring Opening of Bridged Systems. 10.5 Olefin Metathesis. 10.6 Acylation. 10.7 Asymmetric Deprotonation. 10.8 Oxidations. 10.9 Cyclic Anhydride Desymmetrization. 10.10 Miscellaneous. 10.11 Concluding Remarks. Acknowledgments. References. 11 History and Perspective of Chiral Organic Catalysts (Gerald Lelais and David W. C. MacMillan). 11.1 Introduction. 11.2 Historical Background. 11.3 Iminium Catalysis: A New Concept in Organocatalysis. 11.4 Enamine Catalysis: Birth, Rebirth, and Rapid Growth. 11.5 Bronsted Acid Catalysis: Hydrogen-Bonding Activation. 11.6 Phase Transfer Catalysis (PTC). 11.7 Future Perspective. Acknowledgments. References and Notes. 12 Chiral Bronsted/Lewis Acid Catalysts (Kazuaki Ishihara and Hisashi Yamamoto). 12.1 Introduction. 12.2 Chiral Bronsted Acid Catalysts. 12.3 Chiral Lewis Acid Catalysts. 12.4 Lewis Acid--Assisted Chiral Bronsted Acid Catalysts. 12.5 Conclusions and Outlook. References. 13 Chiral Bifunctional Acid/Base Catalysts (Masakatsu Shibasaki and Motomu Kanai) 13.1 Introduction. 13.2 Chiral Bro nsted Base Catalysis. 13.3 Chiral Bronsted Base--Lewis Acid Bifunctional Catalysis. 13.4 Chiral Bronsted Base--Bronsted Acid Bifunctional Catalysis. 13.5 Chiral Lewis Base Catalysis. 13.6 Chiral Lewis Base--Lewis Acid Bifunctional Catalysis. 13.7 Conclusion. References and Notes. Index.