Visible-light induced decarboxylative coupling of redox-active esters with disulfides to construct C-S bonds
Visible-light induced decarboxylative coupling of redox-active esters with disulfides to construct C-S bonds
复制标题
可见光诱导氧化还原活性酯与二硫化物脱羧偶联构建 C-S 键
DOI：
10.1039/d0cc00451k
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发表时间：
2020
影响因子：
4.9
通讯作者：
Zheng Chao
中科院分区：
文献类型：
--
作者：
Xiao Zhiwei;Wang Lu;Wei Junjie;Ran Chongzhao;Liang Steven H.;Shang Jingjie;Chen Guang-Ying;Zheng Chao
建立了一种在钌光氧化还原催化剂存在下，用氧化还原活性酯与二硫键构筑C-S键的新方法。该方法在广泛的底物范围内表现出显着的官能团耐受性。在温和的条件下，通过脱羧交叉偶联，成功地和有效地获得了一系列结构多样的芳基烷基硫醚。
A novel method has been established for the construction of C–S bonds using redox-active esters with disulfides in the presence of Ru-photoredox catalyst. This method exhibits remarkable functional group tolerance across a wide scope of substrates. Under mild conditions, a structurally diverse array of aryl alkyl sulfides is successfully and efficiently obtained through decarboxylative cross-coupling.