Gold corroles
Gold corroles
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DOI：
10.1142/s1088424611003045
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发表时间：
2011-02-01
影响因子：
1.5
通讯作者：
Ghosh, Abhik
中科院分区：
文献类型：
--
作者：
Alemayehu, Abraham B.;Ghosh, Abhik
虽然各种条件证明金插入到β-未取代的meso-三芳基咔咯中是不成功的，但无碱的β-八溴-meso-三芳基咔咯配体H-3[Br 8 T（p-X-P）C]（X = MeO、n-Bu、CH 3、H和CF 3）与氯金酸在含有少量三乙胺的二氯甲烷中反应30分钟导致54-65%产率的相应金络合物。
Although a variety of conditions proved unsuccessful for gold insertion into beta-unsubstituted meso-triarylcorroles, refluxing free-base beta-octabromo-meso-triarylcorrole ligands, H-3[Br8T(p-X-P)C] (X = MeO, n-Bu, CH3, H, and CF3), with chloroauric acid in dichloromethane containing a small amount of triethylamine for 30 min led to 54-65% yields of the corresponding gold complexes.