A Novel Preparation Method of Ni–Sn Alloy Catalysts Supported on Aluminium Hydroxide: Application to Chemoselective Hydrogenation of Unsaturated Carbonyl Compounds

A Novel Preparation Method of Ni–Sn Alloy Catalysts Supported on Aluminium Hydroxide: Application to Chemoselective Hydrogenation of Unsaturated Carbonyl Compounds
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DOI:
10.1246/cl.2012.769
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发表时间:
2012-07
期刊:
影响因子:
1.6
通讯作者:
Rodiansono;Takayoshi Hara;N. Ichikuni;S. Shimazu
Rodiansono;Takayoshi Hara;N. Ichikuni;S. Shimazu
中科院分区:
化学4区
文献类型:
--
作者:
Rodiansono;Takayoshi Hara;N. Ichikuni;S. Shimazu

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采用一种新的方法制备了NiSn合金催化剂,该催化剂用于不饱和羰基化合物的化学选择性加氢,几乎只生成不饱和醇。NiSn合金的形成可能在化学选择性的增强中发挥了关键作用
A novel method was applied for the preparation of NiSn alloy catalysts that were utilized for chemoselective hydrogenation of unsaturated carbonyl compounds, producing unsaturated alcohols almost exclusively. The formation of the NiSn alloy may have played a key role in the enhancement of the chemoselectivity