Controlling stereochemical outcomes of asymmetric processes by catalyst remote molecular functionalizations: chiral diamino-oligothiophenes (DATs) as ligands in asymmetric catalysis.
Controlling stereochemical outcomes of asymmetric processes by catalyst remote molecular functionalizations: chiral diamino-oligothiophenes (DATs) as ligands in asymmetric catalysis.
复制标题
通过催化剂远程分子功能化控制不对称过程的立体化学结果：手性二氨基低聚噻吩（DAT）作为不对称催化中的配体。
作者：
V. Albano;M. Bandini;G. Barbarella;M. Melucci;M. Monari;F. Piccinelli;S. Tommasi;A. Umani
介绍了新型高度通用的手性 C(2)-对称二胺-低聚噻吩配体在 Pd 催化不对称转化中的合成、表征和结构指导应用。描述了悬挂的π共轭低聚噻吩在确定相应手性钯配合物的催化活性中的密切作用的实验研究。它们不寻常的行为为通过远程结构功能化精细调整有机金属催化剂的逻辑设计开辟了新途径。
The synthesis, characterization, and structure-guided application of a new class of highly versatile chiral C(2)-symmetric diamine-oligothiophene ligands in Pd-catalyzed asymmetric transformations are presented. Experimental investigations of the intimate role of pendant pi-conjugate oligothiophenes in determining the catalytic activity of the corresponding chiral Pd complexes are described. Their unusual behavior opens up new routes toward the logical design of finely tuned organometallic catalysts by remote structural functionalizations.
DOI：
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发表时间：
1986
期刊：
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影响因子：
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作者：
T. Skotheim;R. Elsenbaumer;J. Reynolds
通讯作者：
T. Skotheim;R. Elsenbaumer;J. Reynolds