Scattering of Statistical Structure of Polymer/Polymer Interfaces

Scattering of Statistical Structure of Polymer/Polymer Interfaces
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聚合物/聚合物界面统计结构的散射

DOI:
10.1021/ma00088a013
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发表时间:
1994
期刊:
影响因子:
5.5
通讯作者:
A. Semenov
A. Semenov
中科院分区:
化学1区
文献类型:
--
作者:
A. Semenov

文献摘要

被引文献

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本文提出了两种强不相容聚合物之间平界面附近组分涨落的散射理论。它示出的波动的散射引起的表观界面厚度的一个可观的修正。该校正的幅度被示出为关键地取决于特定的实验几何形状(例如,取向界面与随机取向)
A theory for scattering of compositional fluctuations near a flat interface between two strongly incompatible polymers is presented. It is shown that scattering of fluctuations gives rise to an appreciable correction to the apparent interfacial thickness. The magnitude of this correction is shown to be crucially dependent on the particular experimental geometry (e.g., oriented interface vs random orientation)