FERROCENYLPYRIDINES - A NEW SYNTHESIS OF 4'-FERROCENYLTERPYRIDINE AND THE SINGLE-CRYSTAL STRUCTURE OF A C-3-FERROCENOPHANE, [(ETA-C5H4CHCH2C(O)2-C5H4N)2CHC(O)2-C5H4N]FE
FERROCENYLPYRIDINES - A NEW SYNTHESIS OF 4'-FERROCENYLTERPYRIDINE AND THE SINGLE-CRYSTAL STRUCTURE OF A C-3-FERROCENOPHANE, [(ETA-C5H4CHCH2C(O)2-C5H4N)2CHC(O)2-C5H4N]FE
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DOI：
10.1016/0277-5387(94)00266-h
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发表时间：
1995-02-01
期刊：
影响因子：
2.6
通讯作者：
MALIK, KMA
中科院分区：
文献类型：
--
作者：
BUTLER, IR;MCDONALD, SJ;MALIK, KMA
报道了新配体4 ′-二茂铁基三联吡啶的合成与表征，以及一个新的含三个酰基吡啶单元的C-3-二茂铁并菲的合成与表征。以二茂铁甲醛为原料，通过羟醛缩合和环合反应，两步合成了三联吡啶配体。尝试制备类似的1，1 '-双-三联吡啶基二茂铁衍生物导致形成一种新的二茂铁烷：一个双环侧链上产生的阴离子环间攻击另一个双环侧链上的羰基中心的结果。测定了[（eta-C_5 H_4CHCH_2C（O）_2-C_5 H_4 N）（2）CHC（O）_2-C_5 H_4 N] F二氯甲烷溶剂化物[Fe（C_（33）H_（27）N_3 O_3）]·CH_2Cl_2的单晶X射线结构。
The synthesis and characterization of the new ligand 4'-ferrocenylterpyridine is reported together with the synthesis and characterization of a new C-3-ferrocenophane containing three acylpyridine units. The terpyridine ligand was prepared in a two-step synthesis from ferrocenecarbaldehyde by aldol condensation and subsequent cyclization. Attempts to prepare the analogous 1,1'-bis-terpyridylferrocene derivative resulted in the formation of a new ferrocenophane: a consequence of inter-annular attack of an anion generated on the side chain of one cyclopentadienyl ring on a carbonyl centre on the side chain of the other cyclopentadienyl ring. The single crystal X-ray structure of this ferrocenophane, [(eta-C5H4CHCH2C(O)2-C5H4N)(2)CHC(O)2-C5H4N]Fdichloromethane solvate, [Fe(C33H27N3O3)].CH2Cl2, has been determined.