High-rate lithium storage of anatase TiO2 crystals doped with both nitrogen and sulfur

High-rate lithium storage of anatase TiO2 crystals doped with both nitrogen and sulfur
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DOI:
10.1039/c3cc40568k
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发表时间:
2013-01-01
影响因子:
4.9
通讯作者:
Cheng, Hui-Ming
Cheng, Hui-Ming
中科院分区:
化学2区
文献类型:
--
作者:
Jiao, Wei;Li, Na;Cheng, Hui-Ming

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设计并制备了掺杂氮和硫的锐钛矿型TiO 2纳米晶,其中N和S原子分别位于晶体的体相和表层,取代晶格O。由于显著降低的电子电阻,N/S掺杂的TiO 2显示出比参比TiO 2纳米晶体优越的上级高速率锂存储能力,尽管前者具有较大的颗粒尺寸。
Anatase TiO2 nanocrystals doped with nitrogen and sulfur, where substitutional N and S atoms for lattice O, respectively, locate in the bulk and the surface layer of the crystals, were designed and prepared. As a result of remarkably lowered electronic resistance, the N/S doped TiO2 shows a superior high rate lithium storage capability to that of reference TiO2 nanocrystals, though the former has a larger particle size.