An outstanding catalyst for asymmetric transfer hydrogenation in aqueous solution and formic acid/triethylamine

An outstanding catalyst for asymmetric transfer hydrogenation in aqueous solution and formic acid/triethylamine
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DOI:
10.1039/b606288a
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发表时间:
2006-01-01
影响因子:
4.9
通讯作者:
Wills, Martin
Wills, Martin
中科院分区:
化学2区
文献类型:
--
作者:
Matharu, Daljit S.;Morris, David J.;Wills, Martin

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在水溶液和甲酸/三乙胺介质中,Rh/四甲基环戊二烯基络合物在酮的不对称转移氢化反应中均表现出优异的催化性能。
A Rh/tetramethylcyclopentadienyl complex containing a tethered functionality has been demonstrated to give excellent results in the asymmetric transfer hydrogenation of ketones in both aqueous and formic acid/triethylamine media.