Multi-mode Polymerizations Involving Photoinduced Radical Polymerization
Multi-mode Polymerizations Involving Photoinduced Radical Polymerization
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DOI：
10.2494/photopolymer.31.719
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发表时间：
2018-12
影响因子：
0.8
通讯作者：
Gorkem Yılmaz;Y. Yagcı
中科院分区：
文献类型：
--
作者：
Gorkem Yılmaz;Y. Yagcı
多模式聚合为合成嵌段共聚物和接枝共聚物提供了一条简单的途径，这是单一聚合模式无法合成的。在这种聚合策略中，光诱导自由基聚合以其简单、波长灵活、适用范围广、副反应最小等优点发挥着至关重要的作用。本文介绍了光诱导常规聚合和可控活性自由基聚合与其他聚合方法的各种组合，即阳离子聚合、自由基促进阳离子聚合、开环聚合和开环聚合，并对机理细节进行了评估。此外，还讨论了同时或顺序处理的可能性。
Multi-mode polymerizations provide a facile route to synthesis of block and graft copolymers that cannot be made by a single polymerization mode. In such strategy, photoinduced free radical polymerization as one of the polymerization mode play a crucial role due to its simplicity, wavelength flexibility, applicability to wide range of monomers and minimized side reactions. In this article, various combinations of photoinduced conventional and controlled/living radical polymerizations with other polymerization methods, namely cationic, free radical promoted cationic, ring opening, and ring opening metathesis polymerizations are presented and mechanistic details are evaluated. Moreover, the possibilities for the simultaneous or sequential processes are discussed.