Stable cross-linked lyotropic gyroid mesophases from single-head/single-tail cross-linkable monomers

Stable cross-linked lyotropic gyroid mesophases from single-head/single-tail cross-linkable monomers
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DOI:
10.1039/d1cc04211d
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发表时间:
2021-09-27
影响因子:
4.9
通讯作者:
Osuji, Chinedum O.
Osuji, Chinedum O.
中科院分区:
化学2区
文献类型:
--
作者:
Imran, Omar Q.;Li, Patrick;Osuji, Chinedum O.

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一个单头/单尾的表面活性剂与可聚合基团在每个末端作为一个新的简化的主题,本质上是交叉的,回旋相溶致介晶。所得的纳米多孔聚合物网络在各种溶剂中表现出优异的结构稳定性,并且能够进行分子大小区分。
A single-head/single-tail surfactant with a polymerizable group at each end is presented as a new simplified motif for intrinsically cross-linkable, gyroid-phase lyotropic mesogens. The resulting nanoporous polymer networks exhibit excellent structural stability in various solvents and are capable of molecular size discrimination.